JOURNAL OF THE CZECH PHARMACEUTICAL SOCIETY AND THE SLOVAK PHARMACEUTICAL SOCIETY

Čes. slov. farm. 2017, 66(1):9-14 | DOI: 10.36290/csf.2017.002

Gas chromatography - mass spectrometry studies of the component composition of carboxylic acids of the rhizomes of Iris medwedewii and Iris carthaliniae (Iridaceae)

Javanshir I. Isayev1, Оlga O. Mykhailenko2,*, Vladumir M. Kovalyov3, Gamid M. Gurbanov1, Murad Y. Suleymanov4
1 Department of Pharmacognosy and Botany, Azerbaijan Medical University, Baku, Azerbaijan
2 Botany department, National University of Pharmacy, Kharkiv, Ukraine
3 Department of Pharmacognosy, National University of Pharmacy, Kharkiv, Ukraine
4 Analytical Expertise Center, Azerbaijan Republic Ministry of Health, Baku, Azerbaijan

The composition of carboxylic acids of the rhizomes of Iris carthaliniae and Iris medwedewii by the gas chromatography - mass spectrometry method has been studied for the first time. The total content of carboxylic acids for I. carthaliniae was 1.34%, including (%) - 0.65 fatty; 0.36 mono-, di- and tri-carboxylic; 0.33 phenol carboxylic acids. The yield of carboxylic acids for I. medwedewii was 1.58%, including (%) - 0.73 fatty; 0.38 mono-, di- and tri-carboxylic; 0.47 phenol carboxylic acids. The dominant fatty acids in the rhizomes of I. carthaliniae were myristic acid (25%), palmitic acid (14.41%), stearic acid (10.51%) and linoleic acid (6.05%). Besides, levulinic acid (15.84%) and oxalic acid (4.42%) prevailed among organic acids, while ferulic acid (2.43%), citric acid (1.88%) and malic acid (3.62%) prevailed among the hydroxy acids. The fatty acids palmitic acid (6.51%), linoleic acid (8.38%), oleic acid (3.87%) and capric acid (3.21%) were found in the rhizomes of I. medwedewii, and also, levulinic (29.39%), malonic (1.45%), succinic (1.72%) acids prevailed among the organic acids and citric (25.37%), malic (3.30%) and ferulic (2.42%) acids in the rhizomes of I. medwedewii prevailed among the hydroxy acids.

Keywords: Iris carthaliniae; Iris medwedewii; rhizomes; carboxylic acids; GC-MS analysis

Received: November 21, 2016; Accepted: February 16, 2017; Published: January 1, 2017  Show citation

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Isayev JI, Mykhailenko &O, Kovalyov VM, Gurbanov GM, Suleymanov MY. Gas chromatography - mass spectrometry studies of the component composition of carboxylic acids of the rhizomes of Iris medwedewii and Iris carthaliniae (Iridaceae). Čes. slov. farm. 2017;66(1):9-14. doi: 10.36290/csf.2017.002.
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